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But the notion of agate also embraces chalcedony variants that do not show any signs of banding, probably because of the long-term use of names like "moss agate" for stones that would simply be more difficult to sell as "moss chalcedony". It is difficult to draw a line between agate and other types of chalcedony.
- banding of whatever kind, caused by different colors or different structure of the layers, or both
- translucency in conjunction with being multicolored
- translucency in conjunction with a nodular shape and colored inclusions
So an "ideal agate" is a nodule filled with a translucent, multicolored chalcedony with parallel bands. The minimum requirement would be that it is either translucent and exhibits some colored pattern or shows banding.
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This is still not the complete story, as structural considerations also play a role in classifying a specimen. A chert can be both multicolored and slightly translucent, but it will not be called an agate, as it lacks certain structural properties that are typically found in agates. Currently I cannot tell if the structural characteristics of the forementioned "moss agates" are so different that one should rather not call them agates.
Strictly spoken, agate is not a mineral [1]. Agate does not have a homogeneous structure, like a crystal, and it usually isn't even made of a single type of mineral. It resembles a rock made up of different components in varying proportions, but I prefer to call it a textural variety of quartz, like all the other cryptocrystalline quartz varieties.
Specific Properties
Agate can be of any color, the most frequent colors are (in descending order) gray, white, brown, salmon, red, orange, black, and yellow. Shades of violet or a grayish-blue can occur, deep green and blue tones are very unusual, turquoise-colored specimen come from Needles, California. The color is caused by various embedded minerals, of which iron oxides and hydroxides are most common, giving yellow, brown and red colors.Agate has long been known as a porous material that can be dyed easily and numerous methods to change, enhance or add color have been developed. Specimen that lack vivid colors and banding, like many agates from Brazil, are cut into thin slices and artificially "enhanced" with various dyes, yielding deep green, blue, pink, and sometimes more unsuspicious brown tones.
Occasionally agate geodes are found that still have some of the water captured in a central cavity, so called enhydros. You can sometimes hear the water when you shake the specimen. These will slowly loose their water as it escapes through tiny capillaries and evaporates at the surface. There is nothing special about enhydros except for being quite rare, they simply did not dry out yet, like all the other agates did. Remember that agates form in a watery environment.
Banding
The banding is the most characteristic property of agates. It is mostly a result of periodic changes in the translucency of the agate substance - layers appear darker when they are more translucent (this may appear reversed in transmitted light). This effect may be accompanied and amplified by changes in the color of neighboring layers. In old agates that have been subject to weathering and chemical alteration the differences in translucency may disappear.
The thickness of the individual layers varies greatly in different agate specimen. In the finely banded agate from Agate Creek shown in the image below one can count more than 200 layers per centimeter. Other specimen show a much lower density of layers.
- In most agates the wall-lining banding dominates, and in many specimens it is the only type of banding. The banding that is seen in two-dimensional polished cross-sections of agates is only the result of their onion-like composition of concentric layers that follow the shape of the wall of the cavity.
The apparent thickness of a layer depends on the orientation of the cut and varies in a cross section. If one takes this into account, in many agates the layers are spaced evenly and individual layers remain their thickness across the entire specimen. It should be stressed that there is no "rule of equidistance of the layers", as there are striking examples of agates in which the thickness of the layers varies greatly (for example, "Limpopo agates" from Botswana).
- Horizontal banding caused by parallel layers is much less common. It has first been described in agates from Uruguay and therefore is also called Uruguay-type banding and the specimen often simply Uruguay agates. These agates are often used for cutting cameos and engravings when the difference in translucency or color between the layers is pronounced (see also Onyx).
Because of the way they form (which will be explained later), horizontal bands can serve as spirit levels to determine the original orientation of the specimen in the host rock.
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In this section of the specimen the wall-lining layers are homogeneously colored and spaced quite evently. By contrast, the horizontal layers look much more diverse: some layers appear granular and less translucent, one can recognize two areas made of quartz crystals (notice the bright reflections), one layer is colored orange, and in the upper part there is an area with ripple banding. The most interesting and tale-telling feature of horizontal bands are the numerous little particles that apparently have precipitated on some of the layers.
Some, but not all horizontal layers merge with wall-lining layers. So at least some of them did develop independently from the wall-lining banding.
Thin slices of clear agates may exhibit a vivid play of spectral colors when viewed in transmitted light. The colors are caused by a very fine banding that is superimposed on the regular, wall-lining agate banding, and that acts as a diffraction grating on the light (Jones, 1952). The observed colors are interference colors that change with the viewing angle. The strongest effect is seen in sections of less than 1mm thickness that were cut perpendicular to the banding (just as most agates are cut to show their regular banding). The grating is made of alternate layers of slightly higher and lower refractive indices that run parallel to the regular bands (Jones, 1952).
Agates showing interference colors are sometimes called "iris agate" or "rainbow agates", as the iris banding is considered as a special phenomenon that is only found in certain types of agates of a few locations. Studies on agates from different locations indicate that iris banding is a common phenomenon that is usually masked by strong pigmentation or low translucency of the specimen (Jones, 1952; Frondel, 1978; Heaney and Davis, 1995). Agates are also rarely cut into slices that are thin enough for the interference effects to be observed.
Within an agate, iris banding is commonly found in areas close to the transition to drusy, macrocrystalline quartz, an indication that it develops at late periods of the agate formation (Taijing & Sunagawa, 1994).
To cause strong interference effects and bright primary colors, the distance between the elements of the grating must be just a few times larger than the wavelength of light (between 250-700 nm, or 0.25-0.70 micrometers). In optical microscopy studies, Jones observed variations in the spatial frequencies of the banding between 15/mm and 600/mm, corresponding to wavelengths of 67,000 nm and 1670 nm, with the colors getting more saturated the finer the banding is. Similar spacings between the bands, between below 1 and 100 micrometers, were observed by Frondel, 1978, and Taijing and Sunagawa, 1994, with widths of 1-3 micrometers being most common. Iris banding seems to correlate with periodic variations in quartz grain size (Taijing & Sunagawa, 1994) and chemical composition (Frondel, 1978, Heaney and Davis, 1995, see under "Composition").
Composition
Like many other types of chalcedony, even "pure agate" is not necessarily made of pure quartz. It may contain varying amounts of the silica polymorph moganite, typically between 1% and about 20%, mostly around 5% (Heaney and Post, 1992). Of all silica polymorphs moganite shows most structural similarities with quartz, but it is never found in pure form. The moganite content of agates depends on their age, as the moganite slowly converts into quartz, apparently agates older than Silurian age are basically pure quartz (Moxon and Rios, 2002; Moxon, 2004).
A chemical analysis of the total composition of agates shows small amounts of water in addition to silica, typically in the range from 0.5% to 1.5% (as reviewed by Graetsch 1994). Parts of which are captured in the pores between the tiny crystal grains, while some of it is bound chemically in silanole (Si-OH) groups. This water can be partially driven out of the agate by heating to 200-500°C for a couple of hours. The loss of water is apparently in large part due to the decomposition of the silanole groups (Fukuda and Nakashima, 2008).
Individual agates show a zonation of water content (both as silanole-groups and molecular water) parallel to the banding, but often on a much finer scale, with individual compositional bands measuring around 1 micrometer (Frondel, 1982; Frondel, 1985). Submicrometer-scale compositional bands seem to coincide with iris banding (Frondel, 1978). In his studies Frondel (1985) named zones H, M, and L, corresponding to high, medium and low lewels of OH. He found that the compositional zones exhibit peculiar spatial patterns. Zones often show oscillatory variations of OH-content, leading to repetitive and symmetric patterns like "HLMLHLMLHLMLH" or "MHLHLHMHLHLHM" that extend over several millimeters.
Compositional zoning that coincides with iris banding has also been observed by Heaney and Davis, 1995, for aluminum, Al, and sodium, Na. The concentrations of both trace elements correlate, which indicates that Na is trapped in the crystal lattice as a charge compensator for trivalent Al that replaces silicon in the SiO4 groups.
Agate is often said to contain some opal, but this could not be generally confirmed in recent studies (e.g. Heaney et al., 1994). Probably impurities, like the presence of water and the formerly unknown mineral moganite, and lattice defects commonly found in chalcedony distorted the measurements of the structural properties in a way that could be interpreted as presence of some amorphous substance like opal. In a review on the nomenclature of micro- and non-crystalline silica minerals, Flörke et al., 1991, mention opal-C as a typical matrix component in horizontal, Uruguay-type bands in agate. However, in his own review on microcrystalline silica minerals, Graetsch, who is a co-author in the forementioned article, states that "Further investigations have provided no evidence for the presence of opal" (Graetsch, 1994, page 212).
Structure
- length-fast chalcedony or simply chalcedony ( = quartz )
- quartzine, also called length-slow chalcedony ( = quartz )
- pseudochalcedony ( = quartz )
- microquartz ( = quartz )
- moganite (formerly "lutecite")
All agates contain either length-fast chalcedony or microquartz, or both.
Chalcedony, quartzine, pseudochalcedony and microquartz differ in the way their quartz crystallites are intergrown. As explained in detail in the chapter Types of Quartz, they appear to be made of fibers when viewed in polarized light in a microscope (for an overview see Braitsch 1957; Frondel 1978; Flörke et al. 1991; Graetsch 1994; Cady et al. 1998). Their fibrous look is a result of the relative orientation of the crystallites in the matrix, and since there are no real separable fibers in the chalcedony substance, I call them virtual fibers. However, when agate is artificially dyed, the color penetrates the rock much more quickly in the direction parallel to the fibers, which are mostly oriented perpendicular to the banding, than along the layers (Bauer, 1904; Liesegang, 1915), so the term "fibers" is not completely inadequate. Scanning electron microscopy studies have revealed that pores in the chalcedonic substance tend to be arranged along lines parallel to the virtual fibers (Monroe, 1964). Subsequent scanning and transmission electronic microscope studies (Taijing & Sunagawa, 1994) have revealed that virtual fibers are composed of even smaller, slightly elongated crystallites (8-100 nm, invisible in optical microscopy) that are aligned on a much finer scale parallel to the orientation of the virtual fibers.
The dominant component in agate is length-fast chalcedony. Quartzine, microquartz and pseudochalcedony are present in much smaller amounts. As mentioned above under "Composition", the moganite content is highly variable, but usually low.
These components may also be found in other cryptocrystalline quartz varieties, like flint or chrysoprase, so their presence is not special to agates. What is special for agates is that these phases are intergrown in a highly ordered and characteristic manner. In a typical agate, consecutive layers of length-fast chalcedony lie parallel to the banding, with occasional layers of quartzine and areas of pseudochalcedony interspersed. The chalcedony is often intergrown with moganite.
- In the wall-lining layers that characterize agates, length-fast chalcedony and quartzine virtual fibers run roughly perpendicular to the layers, thus perpendicular to the banding: the individual virtual fibers point away from the wall.
- In horizontal layers that characterize Uruguay-type banding the virtual fibers of length-fast chalcedony emanate from single points to form small spheres of radiating virtual fibers.
The individual quartz crystallites of the virtual fibers predominately show Brazil law twinning, both in lenght-fast chalcedony and quartzine (Graetsch, 1994; Taijing & Sunagawa, 1994; Xu et al., 1998). Periodic variations of grain size along the fibers were found to occur in agate parts that show iris banding (Taijing & Sunagawa, 1994).
Occurrence
Agates typically occur in volcanic rocks. They are sometimes found in sedimentary rocks, while occurrences in metamorphic and plutonic rocks are exceptional.
Volcanic Rocks
Agate forms during secondary processes in volcanic rocks, long after these have solidified, and at relatively low temperatures. It fills out cavities in the rock, either isolated geodes of various shapes, or irregular cracks. The shape of the agate nodules also depends on the composition and structure of the volcanic rock.
- in basic volcanic rocks like basalt, rounded, often ellipsoidal cavities formed by gas bubbles in the still molten lava. The agate nodules that formed in these cavities often show a spherical, ellipsoidal or pear-like shape and have a smooth surface. As fresh basalts are poor in silica, the release of silica necessary for agate formation is caused by the weathering of silicates by meteoric and telemagmatic waters and carbon dioxide. In the course of weathering the released calcium will bind the dissolved carbon dioxide to form calcite, and accordingly calcite is a common companion of agates in these rocks.
- in acidic volcanic rocks with a high silica content like rhyolite, irregular, often star-like agates form in cavities in spherical geodes, often called thundereggs. Although usually associated with the western United States, thunderegg-type agates can be found all over the world in silica-rich volcanic rocks. The initial formation of thundereggs is much more complex than the formation of geodes in basalts and takes place at higher temperatures.
Finally, agates can fill irregular cracks in the already solidified lava that have been formed during cooling and shrinking of the rock.
Sedimentary Rocks
Agates can be found in sedimentary rocks. For example, there are several locations in the northern and southern Schwarzwald (Back Forest), where small agates formed in cavities inside chalcedony in a Triassic sandstone (Obenauer, 1979).
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Hydrothermal Veins
Agate is occasionally found as "vein" agate in and around low-temperature hydrothermal veins, for example at certain ore deposits. An interesting combination is sometimes found at the Grube Clara in the Black Forest, Germany, where thin banded layers of chalcedony formed inside cavities of massive fluorite veins.
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Silicified Wood
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The image shows a cross section of a silicified wood branch from an unknown location in India. Cracks in the wood have been filled with colorful agate. While the wood substance has been replaced by yellow chalcedony, probably dyed by hydrous iron oxides, the agate fillings in the voids are stained by reddish hematite. The difference in color indicate that the silicification of the wood and the agate formation took place at different times. The image below shows the core in detail. Collection, photos and copyright Klaus Stubenrauch.
Agate Varieties
The names of agate varieties are chosen more or less arbitrarily according to their visual appearance, usually that of a cut and polished stone - there are no strict rules or definitions. With such a terminology it is no surprise that there is a countless number of agate "varieties", Zenz, 2005, lists 122 different varieties, for example. A few terms are widespread and people agree on their meaning. Some of the names have very little to with the properties of the agate itself, but with the way the agates have been cut: "eye agate" is probably the best example.Language barriers cause more difficulties. A "flame agate" in English is not the same as the literal equivalent "Flammenachat" in German. The same is true for "coral agate" which can be a chalcedony pseudomorph after coral (and thus not really an agate), but also a reddish agate with a certain growth pattern.
Most of the agate names have no mineralogical significance.
Onyx is simply a black-and-white agate and sardonyx a red-white and rarely red-white-black variant. There would probably be no separate name for it if there wasn't a long tradition of cutting cameos from onyx and sardonyx.
Onyx is not to be confused with onyx marble, a banded marble (consisting of calcite, not quartz) used for ornamental works, which is frequently sold as "onyx".
Except for the color, with the black parts being opaque in good specimen, there is nothing specific that cannot be found in other agates. The "ideal onyx" is made of parallel alternating layers of black and white and thus cut from agate of the Uruguay-type.
There is a long tradition of dying agates to turn them into onyx for ornamental and lapidary uses and it can be very hard to tell a real onyx from an artificially dyed one.
Formation
This is going to be a paragraph on agate formation.This is a very difficult and controversial subject and it will take a long time to collect all the necessary informations to write something that really helps. Until then I can only play the "myth buster" and start to list theories and assumptions that do not match the facts.
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The photo shows a very nice example of two agates in one (!) lithophysa from a rhyolite deposit in Sankt Egidien, Sachsen (Saxony), Germany, with a striking difference in their banding pattern and color. The agate is actually a bit darker than shown, I've lightened it up to show the patterns more clearly.
Further Information, Literature, Links
Johann Zenz has written a very nice book, ->Agates, available in German and in English. It gives an overview of worldwide locations and contains about 2000 images of agates.
Locations and Specimen
Of the thousands of agate locations dozens can be considered "classical", and of course it is impossible to cover them comprehensively. The "classical agate countries" are Argentina, Brazil, Germany, Mexico, Morocco, and the U.S.A. I can only present a very small selection of agates.
Australia
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Botswana
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Brazil
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The first image shows the not so common case of two halves of a polygonal agate that was not cut into many slices. The agates are usually made of a thin layer of white, gray or bluish, but hardly ever colorful agate, followed by another layer of quartz crystals that outlines a central cavity. In this specimen the quartz crystals are covered by another thin layer of chalcedony.
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Germany
The classical agate location in Germany is the area around the small town of Idar-Oberstein in the Hunsrück Mountains in Rheinland-Pfalz (Rhineland-Palatinate). For a short overview of the mining history and the geology of the Idar-Oberstein region, see the booklet Die Edelsteinmine im Steinkaulenberg und die historische Weiherschleife in Idar-Oberstein by Bambauer et al., which is also the main source of the information on the local history on this page.
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When immigrants from the Idar-Oberstein area discovered the large agate and amethyst deposits of Brazil and Uruguay in the early 19th century, the local mines were soon abandoned. Nevertheless the plentiful imports from South America sparked off a boom of the local lapidary arts industry in the middle of the 19th century, and today Idar-Oberstein is still an important center in mineral trade and lapidary arts.
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The specimen is shown "as is", it is rough, just as it was when I cracked the rock. The brown outer layer is made of calcite, and the fine banding of the agate is well visible despite its rough surface. Note the large single spherulite in the upper part that predates the formation of the calcite layer.
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Hungary
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Italy
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Mexico
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The black minerals in the upper corner are manganese oxides (like pyrolusite, with tetravalent manganese Mn4+) that also stain the outer part of the agate gray, while bivalent manganese compounds with Mn2+ ions give the inner agate layers a faint pink color.
Morocco
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Namibia
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Good quality lace agate is found in southern Namibia, in the area south-west of Karasburg, in particular at the farm Ysterputz. The image shows a typical tumbled piece.
Poland
Poland has for some time been the sources of excellent agates and is about to become one of the classical agate countries. I only own a few agates from there, and if you want to get a better impression, you can check out the website www.agates.eu, which presents agates from the Sudetes in southern Poland and bordering Czech Republic.
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U.S.A.
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Footnotes
1 I am not talking about "agate" not being a valid mineral name. No quartz variety name counts as a valid mineral name - the valid mineral name for all varieties is "quartz". I′m talking about a specimen being a mineral or not, and that depends on its homogeneity in terms of crystal structure and chemical composition.2 Named after the patron saint of the colliers.
3 Sometimes people say that the name "Steinkaulenberg" is derived from its older name, "Galgenberg" ("gallows mountain"), but it simply is the local dialect form of "Steinkuhlenberg", which translates to "stone hollow mountain" or "stone pit mountain".
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